(TERT-BUTYL)CYCLOPENTADIENYLINDIUM(I), IN(C5H4CME3) - SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURAL STUDY

被引：25

作者：

BEACHLEY, OT ^{[1
]}

LEES, JF ^{[1
]}

ROGERS, RD ^{[1
]}

机构：

[1] NO ILLINOIS UNIV,DEPT CHEM,DE KALB,IL 60115

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 418卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)86363-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The indium(I) compound, In(C5H4CMe3), has been prepared from the corresponding lithium cyclopentadienyl reagent Li(C5H4CMe3) and InCl in OEt2. Characterization data have included partial elemental analyses (C, H), physical properties, IR, H-1 NMR and mass spectroscopic data, oxidation reactions with dilute aqueous HCl and a single-crystal X-ray structural study. The colorless crystal of In(C5H4CMe3) consists of infinite zigzag chains. There are no interstrand In ... In interactions. The compound crystallizes in the monoclinic space group P2(1)/n with four formula units in the unit cell with dimensions of a 6.139(1), b 9.765(6), c 15.543(3) angstrom, beta 92.87(1) and rho-calcd 1.68 g/cm3.

引用

页码：165 / 171

页数：7

共 12 条

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