REACTION OF HETERODINUCLEAR MU-ETHYNEDIYL COMPLEXES CONTAINING PALLADIUM AND PLATINUM - MULTIPLE AND SUCCESSIVE INSERTION OF ISOCYANIDES

被引：67

作者：

ONITSUKA, K ^{[1
]}

JOH, T ^{[1
]}

TAKAHASHI, S ^{[1
]}

机构：

[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 07期

关键词：

D O I：

10.1002/anie.199208511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The living polymerization of aryl isocyanides has been achieved with the PdPt-ethynediyl complexes 1. The molecular weight distributions is very narrow for the polymers 2 (nBAR = 10) and 3 (nBAR = 100), and the same end groups as in complex 1 ensure the living nature of the polymerization. If the ratio of isocyanide to 1 is restricted to 2:1, a double-insertion product can be isolated. R = Et, nBu; Ar = Ph, 4-NO2C6H4 inter alia.

引用

页码：851 / 852

页数：2

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