IS AROMATICITY A USEFUL CONCEPT FOR C-60 AND ITS DERIVATIVES - AROMATIZATION OF C-60 BY REGIOSELECTIVE ADDITION

被引：43

作者：

FOWLER, PW ^{[1
]}

COLLINS, DJ ^{[1
]}

AUSTIN, SJ ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 03期

关键词：

D O I：

10.1039/p29930000275

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Qualitative symmetry arguments, evidence from bondlengths and energies, and from the addition chemistry of C60 point to a localised description of the pi system of this molecule. Regioselective saturation of six double bonds in C60 is predicted to lead to an alternant delocalised (aromatic) pi system that is realised in at least one well characterised compound.

引用

页码：275 / 277

页数：3

共 34 条

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