PHOTOISOMERIZATION OF INDOLINESPIROBENZOPYRAN IN ANIONIC CLAY MATRICES OF LAYERED DOUBLE HYDROXIDES

被引：64

作者：

TAGAYA, H ^{[1
]}

SATO, S ^{[1
]}

KUWAHARA, T ^{[1
]}

KADOKAWA, J ^{[1
]}

MASA, K ^{[1
]}

CHIBA, K ^{[1
]}

机构：

[1] TDK CORP,CTR RES & DEV,NAGANO 38902,JAPAN

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 12期

关键词：

D O I：

10.1039/jm9940401907

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sulfonated indolinespirobenzopyran (SP-SO3-) was intercalated into the Mg/At or Zn/Al layered double hydroxides (LDHs) in the presence of toluene-p-sulfonic acid (PTS). The new intercalates exhibited reversible photoisomerization between SP-SO3- and merocyanine (MC). The presence of PTS was critical for the reversible photoisomerization. MC was very stable and the rate constant of decolorization was <9x10(-7) s(-1). SP interacted with non-polar portions between the layers although MC interacted with the polar interior surface of the LDH.

引用

页码：1907 / 1912

页数：6

共 34 条

[1] INTERACTION OF SMECTITES WITH ORGANIC PHOTOCHROMIC COMPOUNDS [J].