KINETICS;
HYDROGEN;
CARBON MONOXIDE;
METHANE;
MODELING;
OXIDATION;
SUPERCRITICAL WATER OXIDATION;
D O I:
10.1051/jcp/1995921124
中图分类号:
Q5 [生物化学];
Q7 [分子生物学];
学科分类号:
071010 ;
081704 ;
摘要:
The kinetics of the supercritical oxidation of hydrogen, carbon monoxide, and methane was modeled using a detailed chemical kinetic reaction mechanism initially validated for the combustion of these fuels and of natural gas in the gas phase. The concentration profiles of reactants and products measured at MIT in a plug flow reactor have been used to validate a detailed kinetic reaction mechanism in supercritical conditions.