NEW OXIDATIVE AROMATIZATION OF ALPHA,BETA-UNSATURATED CYCLOHEXENONES WITH IODINE-CERIUM(IV) AMMONIUM-NITRATE IN ALCOHOL

被引：25

作者：

HORIUCHI, CA

FUKUNISHI, H

KAJITA, M

YAMAGUCHI, A

KIYOMIYA, H

KIJI, S

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 11期

关键词：

D O I：

10.1246/cl.1991.1921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2-cyclohexen-1-one derivatives with iodine-cerium(IV) ammonium nitrate in alcohols (methanol, ethanol, 1-propanol, 2-propanol, and 1-butanol) under refluxing, gave the corresponding alkyl phenyl ethers in good yields. In the case of diol (ethylene glycol, 1,3-propanediol, and 1,4-butanediol), phenoxyalkanol derivatives were obtained. The present method was also applicable to oxidative rearrangement of isophorone.

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页码：1921 / 1924

页数：4

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