LEWIS ACID-CATALYZED ENE REACTIONS OF ESTERS OF 2-TRIFLUOROMETHYLPROPENOIC ACID

被引：8

作者：

HANZAWA, Y ^{[1
]}

SUZUKI, M ^{[1
]}

SEKINE, T ^{[1
]}

MURAYAMA, T ^{[1
]}

TAGUCHI, T ^{[1
]}

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In Lewis acid-catalysed ene reactions of esters (1 and 2) of 2-trifluoromethylpropenoic acid, the high reactivity of 1 and 2 and preparation of an optically active trifluoromethylated tertiary carbon (S-configuration, > 80% diastereoisomeric excess) by TiCl4-catalysed ene reactions of 2 are reported.

引用

页码：721 / 722

页数：2

共 8 条

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