NMR SPINNING SIDE-BAND AND SPIN ECHOES - IMAGING OF COUETTE-FLOW

被引:12
作者
HOPKINS, JA
GRUTZNER, JB
机构
[1] Department of Chemistry, Purdue University, West Lafayette
关键词
D O I
10.1006/jmra.1994.1220
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The sidebands generated by a cylindrical sample spinning in a linear gradient under Hahn spin-echo conditions are examined experimentally and theoretically. Explicit expressions are developed for the phase and intensity of the magnetization as a function of time. When the signals are sampled stroboscopically with the echo time matched to multiples of the rotation period, a standard spinning-sideband pattern is observed. Intermediate pulse delays result in a decrease in sideband intensity and nonlinear phase distortions across the pattern. The stroboscopic sampling technique is applied to Couette shear flow to selectively detect slices from the fluid on the basis of angular velocity. The imaged annular slices may then be analyzed spectroscopically. (C) 1994 Academic Press, Inc.
引用
收藏
页码:17 / 22
页数:6
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