SYNTHESIS AND STRUCTURAL FEATURES OF NEW [5,7]ORTHOCYCLOPHANES, [7,7]CYCLOPHANES AND CORRESPONDING MACROBICYCLIC CRYPTOPHANES

被引：13

作者：

BAUCHAT, P

LEBRAS, N

RIGAL, L

FOUCAUD, A

机构：

[1] UNIV RENNES 1,CNRS,CHIM STRUCT GRP,F-35042 RENNES,FRANCE

[2] ECOLE NATL SUPERIEURE CHIM,CHIM AGROIND LAB,F-31077 TOULOUSE,FRANCE

来源：

TETRAHEDRON | 1994年 / 50卷 / 26期

关键词：

D O I：

10.1016/S0040-4020(01)85265-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Baylis-Hillman reaction of dialdehydes with methyl acrylate, followed by acetylation of the resulting diols gave diacetates 3, 14, 16 and 20. Treated with ammonia, these diacetates afforded new cyclophanes and the corresponding macrobicyclic cryptophanes. Conformational analysis of the cyclophanes was described.

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页码：7815 / 7826

页数：12

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