CERIUM(III) AND NEODYMIUM(III) PICRATE COMPLEXES WITH TETRAMETHYLUREA

被引：8

作者：

BARBERATO, C ^{[1
]}

CASTELLANO, EE ^{[1
]}

VICENTINI, G ^{[1
]}

ISOLANI, PC ^{[1
]}

LIMA, MIR ^{[1
]}

机构：

[1] UNIV SAO PAULO,INST QUIM,BR-01498970 SAO PAULO,BRAZIL

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193008765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In both title complexes, tris(1,1,2,2-tetramethyl-urea-kappaO)tris(2,4,6-trinitrophenolato-kappaO,O')cerium-(III), [Ce(C6H2N3O7)3(C5H12N2O)3] (1), and tris-(1,1,2,2-tetramethylurea-kappaO)tris(2,4,6-trinitropheno-lato-kappaO,O')neodymium(III), [Nd(C6H2N3O7)3(C5-H12N2O) 3] (2), the lanthanide ion is coordinated to three bidentate picrate and three monodentate tetramethylurea (TMU) groups in a distorted tricapped-trigonal prismatic geometry.

引用

页码：351 / 354

页数：4