STUDY OF A THIN-FILM ELECTROCHEMICAL-CELL BASED ON (PVP+AGNO3) ELECTROLYTE

被引：25

作者：

REDDY, MJ

RAO, SS

LAXMINARSAIAH, E

RAO, UVS

机构：

[1] Department of Physics, Osmania University, Hyderabad

来源：

SOLID STATE IONICS | 1995年 / 80卷 / 1-2期

关键词：

ELECTROCHEMICAL CELLS; POLYMER ELECTROLYTES; PVP; THIN FILMS;

D O I：

10.1016/0167-2738(95)00128-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new silver ion conducting polymer electrolyte based on polyvinylpyrrolidone (PVP) complexed with AgNO3 has been prepared using solution-cast technique. IR, electrical conductivity and transference number measurements have been performed to characterize the polymer electrolyte. The transport number measurements have shown that the electrolyte is a mixed (ionic + electronic) conductor, the charge transport being mainly due to ionic (t(100) similar or equal to 0.94). Using the electrolyte, an electrochemical cell with the configuration Ag/PVP + AgNO3/(I-2 + C + electrolyte) has been fabricated and its discharge characteristics studied. The open circuit voltage (OCV) and short circuit current (SCC) observed for the cell are 460 mV and 65 mu A respectively. A number of other cell parameters evaluated are also reported.

引用

收藏

页码：93 / 98

页数：6

相关论文

共 23 条

[1] POLYPHOSPHAZENE-POLY(OLEFIN OXIDE) MIXED POLYMER ELECTROLYTES .1. CONDUCTIVITY AND THERMAL STUDIES OF MEEP/PEO-(LIX)N [J].

ABRAHAM, KM ;

ALAMGIR, M ;

REYNOLDS, RK .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (12) :3576-3582

[2] THIN-FILM SOLID-STATE POLYMER ELECTROLYTES CONTAINING SILVER, COPPER AND ZINC IONS AS CHARGE-CARRIERS [J].

ABRANTES, TMA ;

ALCACER, LJ ;

SEQUEIRA, CAC .

SOLID STATE IONICS, 1986, 18-9 :315-320

[3]

BLONSKY PM, 1987, CHEMTECH, V758

[4] AN ANHYDROUS POLYMER ELECTROLYTE CONTAINING TRIVALENT CATIONS - POLY(ETHYLENE OXIDE) - LA(CLO4)3 [J].

BRUCE, PG ;

NOWINSKI, J ;

GRAY, FM ;

VINCENT, CA .

SOLID STATE IONICS, 1990, 38 (3-4) :231-234

[5] INVESTIGATIONS ON POLY ETHYLENE-OXIDE BASED POLYMER ELECTROLYTE COMPLEXED WITH AGNO3 [J].

CHANDRA, S ;

HASHMI, SA ;

SALEEM, M ;

AGRAWAL, RC .

SOLID STATE IONICS, 1993, 67 (1-2) :1-7

[6] SOLID-STATE PROTONIC CONDUCTORS - COMPLEXATION OF POLY(ETHYLENE OXIDE) OR POLY(ACRYLIC ACID) WITH NH4HSO4 [J].

DANIEL, MF ;

DESBAT, B ;

LASSEGUES, JC .

SOLID STATE IONICS, 1988, 28 :632-636

[7] PHASE-DIAGRAM, CONDUCTIVITY, AND TRANSFERENCE NUMBER OF PEO-NAL ELECTROLYTES [J].

FAUTEUX, D ;

LUPIEN, MD ;

ROBITAILLE, CD .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (11) :2761-2767

[8] NMR, DSC AND ELECTRICAL-CONDUCTIVITY STUDIES OF MEEP COMPLEXED WITH NACF3SO3 [J].

GREENBAUM, SG ;

ADAMIC, KJ ;

PAK, YS ;

WINTERSGILL, MC ;

FONTANELLA, JJ .

SOLID STATE IONICS, 1988, 28 :1042-1046

[9] NMR, DSC, DMA, AND HIGH-PRESSURE ELECTRICAL-CONDUCTIVITY STUDIES IN PPO COMPLEXED WITH SODIUM-PERCHLORATE [J].

GREENBAUM, SG ;

PAK, YS ;

WINTERSGILL, MC ;

FONTANELLA, JJ ;

SCHULTZ, JW ;

ANDEEN, CG .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (01) :235-238

[10] POLY(ETHYLENE OXIDE) COMPLEXES OF LEAD HALIDES - NEW POLYMERIC CONDUCTORS OF PB-2+ [J].

HUQ, R ;

CHIODELLI, G ;

FERLONI, P ;

MAGISTRIS, A ;

FARRINGTON, GC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (02) :364-369