Recent advances in inorganic solid electrolytes for lithium batteries

被引:287
作者
Cao, Can [1 ,2 ]
Li, Zhuo-Bin [2 ]
Wang, Xiao-Liang [2 ]
Zhao, Xin-Bing [1 ]
Han, Wei-Qiang [1 ,2 ,3 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, 38 Zheda Rd, Hangzhou, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo, Zhejiang, Peoples R China
[3] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai, Peoples R China
来源
FRONTIERS IN ENERGY RESEARCH | 2014年
基金
中国国家自然科学基金;
关键词
all-solid-state; lithium batteries; inorganic electrolytes; ion conductivity; interface;
D O I
10.3389/fenrg.2014.00025
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The review presents an overview of the recent advances in inorganic solid lithium ion conductors, which are of great interest as solid electrolytes in all -solid-state lithium batteries. It is focused on two major categories: crystalline electrolytes and glass-based electrolytes. Important systems such as thio-LISICON Li10SnP2S12, garnet Li7La3Zr2O12, perovskite Li3xLa(2/3)-xTiO3, NASICON Li1.3Al0.3Ti1.7(PO4)(3), and glass ceramic xLi(2)S center dot(1 - x)P2S5 and their progress are described in great detail. Meanwhile, the review discusses different ongoing strategies on enhancing conductivity, optimizing electrolyte/electrode interface, and improving cell performance.
引用
收藏
页数:10
相关论文
共 96 条
[1]   Investigations on pure and Ag doped lithium lanthanum titanate (LLTO) nanocrystalline ceramic electrolytes for rechargeable lithium-ion batteries [J].
Abhilash, K. P. ;
Selvin, P. Christopher ;
Nalini, B. ;
Nithyadharseni, P. ;
Pillai, B. C. .
CERAMICS INTERNATIONAL, 2013, 39 (02) :947-952
[2]   Effect of substitution (Ta, Al, Ga) on the conductivity of Li7La3Zr2O12 [J].
Allen, J. L. ;
Wolfenstine, J. ;
Rangasamy, E. ;
Sakamoto, J. .
JOURNAL OF POWER SOURCES, 2012, 206 :315-319
[3]  
Alonso JA, 2000, ANGEW CHEM INT EDIT, V39, P619, DOI 10.1002/(SICI)1521-3773(20000204)39:3<619::AID-ANIE619>3.0.CO
[4]  
2-O
[5]   IONIC-CONDUCTIVITY OF SOLID ELECTROLYTES BASED ON LITHIUM TITANIUM PHOSPHATE [J].
AONO, H ;
SUGIMOTO, E ;
SADAOKA, Y ;
IMANAKA, N ;
ADACHI, G .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (04) :1023-1027
[6]   SYNTHESIS AND ELECTROCHEMICAL PROPERTIES OF LITHIUM ION CONDUCTIVE GLASS, LI3PO4-LI2S-SIS2 [J].
AOTANI, N ;
IWAMOTO, K ;
TAKADA, K ;
KONDO, S .
SOLID STATE IONICS, 1994, 68 (1-2) :35-39
[7]   The effect of sintering on the grain boundary conductivity of lithium lanthanum titanates [J].
Ban, CW ;
Choi, GM .
SOLID STATE IONICS, 2001, 140 (3-4) :285-292
[8]   The fast lithium-ion conducting oxides Li3xLa2/3-xTiO3 from fundamentals to application [J].
Bohnke, Odile .
SOLID STATE IONICS, 2008, 179 (1-6) :9-15
[9]   Li10SnP2S12: An Affordable Lithium Superionic Conductor [J].
Bron, Philipp ;
Johansson, Sebastian ;
Zick, Klaus ;
auf der Guenne, Joern Schmedt ;
Dehnen, Stefanie ;
Roling, Bernhard .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (42) :15694-15697
[10]   Ionic conductivity, lithium insertion and extraction of lanthanum lithium titanate [J].
Chen, CH ;
Amine, K .
SOLID STATE IONICS, 2001, 144 (1-2) :51-57