ELECTROSYNTHESIS OF AMINO-ACIDS FROM A MOLYBDENUM NITRIDE VIA NITROGEN CARBON AND CARBON CARBON BOND FORMATION REACTIONS INVOLVING IMIDES AND NITROGEN YLIDES - X-RAY STRUCTURE OF TRANS-[MOCL(NCHCO2ME)(PH2PCH2CH2PPH2)2].CH2CL2

被引：21

作者：

HUGHES, DL ^{[1
]}

IBRAHIM, SK ^{[1
]}

MACDONALD, CJ ^{[1
]}

ALI, HM ^{[1
]}

PICKETT, CJ ^{[1
]}

机构：

[1] UNIV SUSSEX,INST PLANT SCI RES,AFRC,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001762

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sequential nitrogen-carbon and carbon-carbon bond formation, and an electrochemical Mo-N bond cleavage step, define a pathway to methyl esters of the amino acids glycine and alanine from the molybdenum nitride trans-[MoCl(N)(Ph2PCH2CH2PPh2)2], a key intermediate being the metallo-nitrogen ylide trans-[MoCl(NCHCO2Me)(Ph2PCH2CH2PPh2)2], the structure of which has been determined crystallographically.

引用

页码：1762 / 1763

页数：2

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