PHOTOLYSIS OF 2-AMINO-2'-AZIDOBIPHENYLS - FORMAL FORMATION OF INTERNALLY TRAPPED DIDEHYDROAZEPINES

被引：5

作者：

MURATA, S ^{[1
]}

TSUJI, H ^{[1
]}

TOMIOKA, H ^{[1
]}

机构：

[1] MIE UNIV, FAC ENGN, CHEM DEPT MAT, TSU, MIE 514, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 03期

关键词：

D O I：

10.1246/bcsj.67.895

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of 2-amino-2'-azidobiphenyls iii diethylamine gave 4,10-dihydroazepino[2,3-b]indoles (7), the structure of which corresponded to the didehydroazepines formally trapped with an internal amino group. However, the yields of 7 were considerably low, which was due to the significant intramolecular interaction of the photolytically generated nitrene with an amino group, to afford benzo[c]-cinnoline as a final product.

引用

页码：895 / 897

页数：3

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