IN-SITU RAMAN-SPECTROSCOPY DURING DIAMOND GROWTH IN A MICROWAVE PLASMA REACTOR

被引:26
作者
FAYETTE, L [1 ]
MARCUS, B [1 ]
MERMOUX, M [1 ]
ROSMAN, N [1 ]
ABELLO, L [1 ]
LUCAZEAU, G [1 ]
机构
[1] ENSEEG,LIESG,F-38402 ST MARTIN DHERES,FRANCE
关键词
D O I
10.1063/1.357740
中图分类号
O59 [应用物理学];
学科分类号
摘要
An experimental set-up designed for in situ Raman analysis during the growth of diamond films in a microwave plasma reactor is described. A gated multichannel detection synchronized with a pulsed YAG laser is used to discriminate the Raman signals from the plasma emission. The in situ detection of a diamond film during its growth on a single crystal of alumina substrate is presented. The detectivity of the method has been estimated to be about a few tens of mug/cm2 for an acquisition time of 800 s. Peak shifts are interpreted in terms of temperature and stress dependences. It is shown that the diamond in the first stages of deposition is free of stress, then when grains come into contact compressive stresses are observed, when the film thickness reaches about 1 mum stresses are relaxed.
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页码:1604 / 1608
页数:5
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