ON THE PROPOSED EXISTENCE OF A KETENE DERIVED FROM CARBON-MONOXIDE AND 1,3-DI-1-ADAMANTYLIMIDAZOL-2-YLIDENE

被引：41

作者：

DIXON, DA

ARDUENGO, AJ

DOBBS, KD

KHASNIS, DV

机构：

[1] Contribution 7021 from The DuPont Science and Engineering Laboratory, Experimental Station, Wilmington

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 05期

关键词：

D O I：

10.1016/0040-4039(94)02341-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of carbon monoxide with the stable carbene, 1,3-di-1-adamantylimidazol-2-ylidene, is reinvestigated experimentally. With the aid of high level ab initio density functional theory calculations the predicted stability of the putative ketene product is determined. No evidence is found for the existence of a stable ketene product.

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页码：645 / 648

页数：4

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