VIBRATIONAL OVERTONE SPECTRA OF MONOFLUOROACETYLENE - A PRELIMINARY-REPORT

被引：48

作者：

HOLLAND, JK

NEWNHAM, DA

MILLS, IM

机构：

[1] Department of Chemistry, University of Reading, Reading

来源：

MOLECULAR PHYSICS | 1990年 / 70卷 / 02期

关键词：

D O I：

10.1080/00268979000101021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High-resolution infrared and near-infrared spectra have been observed for more than 80 overtone bands of the HCCF molecule, including two CH stretching overtones in the visible region. Many of these have been analysed, and many more are in the course of analysis and will be reported later. All fundamentals have now been rotationally analysed and the equilibrium rotational constant determined. These data provide a testing ground for anhar-monic force-field analyses, and they are discussed briefly in this connection. © 1990 Taylor & Francis Ltd.

引用

收藏

页码：319 / 330

页数：12

相关论文

共 19 条

[1] IR-SPECTRUM OF HCCF AROUND 17 MU-M/ MU-M [J].

ANTTILA, R ;

KAUPPINEN, J ;

RUOTSALAINEN, H .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1977, 66 (01) :87-98

[2] C-H LOCAL MODES IN CYCLOBUTENE .2. LASER PHOTOACOUSTIC STUDIES 10000-17000 CM-1 - VIBRATIONAL STRUCTURE AND C-H LOCAL MODE-DYNAMICS [J].

BAGGOTT, JE ;

LAW, DW ;

LIGHTFOOT, PD ;

MILLS, IM .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (10) :5414-5429

[3] NUMBER OF MULTIPLY-RESTRICTED PARTITIONS [J].

BEYER, T ;

SWINEHART, DF .

COMMUNICATIONS OF THE ACM, 1973, 16 (06) :379-379

[4] SPECTROSCOPY AND VIBRATIONAL COUPLINGS IN THE 3-NU-3 REGION OF ACETYLENE [J].

HERMAN, M ;

HUET, TR ;

VERVLOET, M .

MOLECULAR PHYSICS, 1989, 66 (02) :333-353

[5] HIGH-RESOLUTION IR-SPECTRUM OF V4 BAND OF DCCF [J].

HUHANANTTI, M ;

ANTTILA, R ;

KAUPPINEN, J .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1977, 66 (01) :46-54

[6] INVESTIGATION OF STRUCTURE OF NU-5 BAND OF MONOFLUOROACETYLENE [J].

HUHANANTTI, M ;

KAUPPINEN, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1975, 30 (08) :1039-1043

[7] INFRARED SPECTRA AND POTENTIAL CONSTANTS OF SOME MONOHALOACETYLENES [J].

HUNT, GR ;

WILSON, MK .

JOURNAL OF CHEMICAL PHYSICS, 1961, 34 (04) :1301-&

[8] INFRARED-MICROWAVE DOUBLE-RESONANCE SPECTROSCOPY OF DEUTEROFLUOROACETYLENE [J].

JONES, H .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1983, 102 (02) :498-501

[9] LASER-MICROWAVE 2-PHOTON AND DOUBLE-RESONANCE SPECTROSCOPY OF 2 LINEAR-MOLECULES - HCCF AND FCN [J].

JONES, H .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1979, 78 (03) :452-468

[10]

JONES H, 1978, Z NATURFORSCH A, V34, P340