THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF THE FIRST METAL-1,3,2,4-DITHIADIAZOLYLIUM SALT, [HG(CNSNS)(2)][ASF6](2), A TRANSFER AGENT FOR THE DITHIADIAZOLYLIUM RING

被引：9

作者：

BANISTER, AJ ^{[1
]}

LAVENDER, I ^{[1
]}

LAWRENCE, SE ^{[1
]}

RAWSON, JM ^{[1
]}

CLEGG, W ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 01期

关键词：

D O I：

10.1039/c39940000029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of two equivalents of [SNS][AsF6] with Hg(CN)(2) yields [Hg(CNSNS)(2)][AsF6](2) 1, the first example of a dithiadiazolylium ring bonded to a metal centre via the carbon; the reaction of 1 with iodine and bromine gave the hexafluoroarsenates(v) of [I-CNSNS](+) and previously unreported [Br-CNSNS](+), thereby demonstrating the potential of 1 as a transfer reagent for the dithiadiazolylium cation.

引用

页码：29 / 30

页数：2

共 15 条

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