OXIDATIVE DEHYDROGENATION OF ETHYLENEDIAMINE COORDINATED TO RUTHENIUM WITH HEXAFLUOROACETYLACETONATE, INDUCED BY ELECTROCHEMICAL OXIDATION OF RUTHENIUM(II) TO RUTHENIUM(III)

被引：7

作者：

HOSHINO, Y ^{[1
]}

OKUYAMA, F ^{[1
]}

NANBA, A ^{[1
]}

SHIMIZU, K ^{[1
]}

SATO, GP ^{[1
]}

机构：

[1] SOPHIA UNIV, FAC SCI & TECHNOL, DEPT CHEM, CHIYODA KU, TOKYO 102, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 03期

关键词：

D O I：

10.1246/bcsj.65.876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two mixed-ligand complexes, [Ru(hfac)2(en)] and [Ru(hfac)(en)2]PF6 (en = ethylenediamine and hfac- = hexafluoroacetylacetonate ion), were synthesized. The oxidative dehydrogenation of their en ligand was studied in acetonitrile solutions. Each complex underwent a Nernstian one-electron oxidation at platinum electrodes. The resultant ruthenium(III) species was converted through a series of slow homogeneous reactions into the corresponding 1,2-diiminoethane ruthenium(II) species. Voltammograms recorded during the course of the reactions suggested the presence of 2-amino-1-iminoethane ruthenium(II) intermediates.

引用

页码：876 / 881

页数：6

共 18 条

[1] SYNTHESIS AND PROPERTIES OF SOME TETRAAMMINERUTHENIUM(II) COMPLEXES OF BIDENTATE LIGANDS, CIS-RU(NH3)4(X-Y)2+ [J].

ALVAREZ, VE ;

ALLEN, RJ ;

MATSUBAR.T ;

FORD, PC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (25) :7686-7692

[2] STEPWISE DEHYDROGENATION OF A RU(III) HEXAAMINE CAGE COMPLEX TO A HEXAIMINE RU(II) COMPLEX VIA RU(IV) INTERMEDIATES [J].

BERNHARD, P ;

SARGESON, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :597-606

[3] SYNTHESIS AND CHARACTERISATION OF DIACIDOBIS(ETHYLENEDIAMINE)RUTHENIUM(3) COMPLEXES AND RELATED COMPOUNDS [J].

BROOMHEAD, JA ;

KANEMAGU.LA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (04) :546-+

[4] SUBSTITUTION REACTIONS OF RUTHENIUM(3)-ETHYLENEDIAMINE AND RELATED COMPLEXES .I. ACID HYDROLYSIS OF CIS-DIHALOGENOBIS(ETHYLENEDIAMINE) (-)-1,2-DIAMINOPROPANE TRIETHYLENETETRAMINE AND AND AMMONIA COMPLEXES [J].

BROOMHEAD, JA ;

KANEMAGU.L .

INORGANIC CHEMISTRY, 1968, 7 (12) :2519-+

[5] OXIDATION OF COORDINATED DIAMINES IN BIS(2,2'-BIPYRIDINE) COMPLEXES OF RUTHENIUM [J].

BROWN, GM ;

WEAVER, TR ;

KEENE, FR ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1976, 15 (01) :190-196

[6] CONVENIENT SYNTHESIS OF TRANS-DICHLOROTETRAAMINERUTHENIUM(III) CATIONS [J].

CHAN, PK ;

ISABIRYE, DA ;

POON, CK .

INORGANIC CHEMISTRY, 1975, 14 (10) :2579-2580

[7] RUTHENIUM PROMOTED OXIDATION OF AMINES [J].

DIAMOND, SE ;

TOM, GM ;

TAUBE, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) :2661-2664

[8] A DEPROTONATED ETHYLENEDIAMINE COMPLEX OF RUTHENIUM [J].

ELSBERND, H ;

BEATTIE, JK .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (16) :2598-&

[9] A NEW SYNTHETIC METHOD FOR RUTHENIUM COMPLEXES OF BETA-DIKETONES FROM RUTHENIUM BLUE SOLUTION AND THEIR PROPERTIES [J].

ENDO, A ;

KAJITANI, M ;

MUKAIDA, M ;

SHIMIZU, K ;

SATO, GP .

INORGANICA CHIMICA ACTA, 1988, 150 (01) :25-34

[10] A NEW METHOD FOR SYNTHESIS OF RUTHENIUM(III) AND RUTHENIUM(II) COMPLEXES OF BETA-DIKETONES FROM RUTHENIUM BLUE SOLUTION [J].

ENDO, A ;

SHIMIZU, K ;

SATO, GP ;

MUKAIDA, M .

CHEMISTRY LETTERS, 1984, (03) :437-440

← 1 2 →