THE STRUCTURES OF BIOACTIVE CYCLODEPSIPEPTIDES, BEAUVERIOLIDE-I AND BEAUVERIOLIDE-II, METABOLITES OF ENTOMOPATHOGENIC FUNGI BEAUVERIA SP

被引：49

作者：

MOCHIZUKI, K ^{[1
]}

OHMORI, K ^{[1
]}

TAMURA, H ^{[1
]}

SHIZURI, Y ^{[1
]}

NISHIYAMA, S ^{[1
]}

MIYOSHI, E ^{[1
]}

YAMAMURA, S ^{[1
]}

机构：

[1] KEIO UNIV, FAC SCI & TECHNOL, DEPT CHEM, KOHOKU KU, YOKOHAMA, KANAGAWA 223, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 10期

关键词：

D O I：

10.1246/bcsj.66.3041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Among the cyclodepsipeptides, beauveriolides I (1) and II (2) have been isolated from the mycelium of Beauveria sp., and their stereostructures were elucidated by spectral analyses coupled with syntheses of the corresponding 3-hydroxyoctanoic acid derivatives. Beauveriolide I (1) exhibited moderate insecticidal activities against Spodoptera litura and Callosobruchus chinensis.

引用

页码：3041 / 3046

页数：6

共 10 条

[1] KMNO4 REVISITED - OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS IN THE TERT-BUTYL ALCOHOL AQUEOUS NAH2PO4 SYSTEM [J].

ABIKO, A ;

ROBERTS, JC ;

TAKEMASA, T ;

MASAMUNE, S .

TETRAHEDRON LETTERS, 1986, 27 (38) :4537-4540

[2]

AEBI JD, 1983, LIEBIGS ANN CHEM, P2114

[3] CYCLODEPSIPEPTIDES FROM BEAUVERIA-BASSIANA-BALS .1. BEAUVEROLIDE-H AND BEAUVEROLIDE-I [J].

ELSWORTH, JF ;

GROVE, JF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (03) :270-273

[4]

FRANCOIS F, 1978, PHYTOCHEMSITRY, V17, P545

[5]

FRANCOIS F, 1975, PHYTOCHEMISTRY, V14, P2703

[6]

HALL RA, 1981, MICROBIAL CONTROL PL, P442

[7] PHEROMONE SYNTHESIS .35. STEREOSELECTIVE SYNTHESIS OF OPTICALLY-ACTIVE FORMS OF DELTA-MULTISTRIATIN, THE ATTRACTANT FOR EUROPEAN POPULATIONS OF THE SMALLER EUROPEAN ELM BARK BEETLE [J].

MORI, K ;

IWASAWA, H .

TETRAHEDRON, 1980, 36 (01) :87-90

[8] TRIMETHYLSILYLDIAZOMETHANE [J].

SHIOIRI, T ;

AOYAMA, T .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1986, 44 (02) :149-159

[9] EFFICIENT INVERSIONS OF SECONDARY ALCOHOLS USING CESIUM ACETATE AND 18-CROWN-6 [J].

TORISAWA, Y ;

OKABE, H ;

IKEGAMI, S .

CHEMISTRY LETTERS, 1984, (09) :1555-1556

[10]

TUNER WB, 1971, FUNGAL METABOLITES, P18

← 1 →