KINETICS AND MECHANISM OF THE PUDOVIK REACTION

被引:17
作者
CHERKASOV, RA
GALKIN, VI
KHABIBULLINA, AB
ALKURDI, K
机构
[1] Kazan State University, Kazan
来源
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 49卷 / 1-4期
关键词
D O I
10.1080/10426509008038907
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The kinetics and the mechanism of the Pudovik reaction for the series of α, β-unsaturated carbonyl compounds have been studied. The factors which determine theaddition locoselectivity and the reactivity of the hydrophosphoryl and unsaturated compoundsin this process are established. The qualitative and quantitative relationships obtained allow to predict the reaction rate and its direction depending on the reagents structure and also on the nature of catalyst and solvent used. © 1990, Taylor & Francis Group, LLC. All rights reserved.
引用
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页码:61 / 64
页数:4
相关论文
共 10 条
[1]  
ARBUSOV BA, 1974, IZV AN SSSR C, V11, P2630
[2]  
ARBUSOV BA, 1975, IZV AN SSSR C, V6, P1391
[3]  
GALKIN VI, 1987, DOKL AKAD NAUK SSSR+, V292, P619
[4]  
GALKIN VI, 1983, DOKL AKAD NAUK SSSR+, V268, P105
[5]  
GALKIN VI, 1988, ZH OBSHCH KHIM+, V58, P1002
[6]  
GALKIN VI, 1987, DOKL AKAD NAUK SSSR+, V296, P107
[7]  
Galkin VI., 1981, REAKTSIONNAYA SPOSOB, V18, P111
[8]  
PUDOVIK AN, 1983, ZH OBSHCH KHIM+, V53, P2456
[9]  
PUDOVIK AN, 1978, ZH OBSHCH KHIM+, V48, P487
[10]  
TUDRII GA, 1978, ZH OBSHCH KHIM+, V48, P542