MEASUREMENT OF HEAVY ISOTOPE ENRICHMENT IN TROPOSPHERIC OZONE

被引:149
作者
KRANKOWSKY, D [1 ]
BARTECKI, F [1 ]
KLEES, GG [1 ]
MAUERSBERGER, K [1 ]
SCHELLENBACH, K [1 ]
STEHR, J [1 ]
机构
[1] UNIV MINNESOTA, SCH PHYS & ASTRON, MINNEAPOLIS, MN 55455 USA
关键词
D O I
10.1029/95GL01436
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Tropospheric ozone samples collected during a twelve-month period in urban air show an enrichment of about 9% in the heavy isotope O-50(3) consistent with predictions from laboratory measurements. The enhancement of about 7% observed in O-49(3) is still within the uncertainty of the expected value. These measurements confirm that the isotope effect, repeatedly found in laboratory experiments, is also produced in the atmosphere during the ozone formation process.
引用
收藏
页码:1713 / 1716
页数:4
相关论文
共 21 条
[1]   OZONE ABSORPTION-SPECTROSCOPY IN SEARCH OF LOW-LYING ELECTRONIC STATES [J].
ANDERSON, SM ;
MAUERSBERGER, K .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1995, 100 (D2) :3033-3048
[2]   LABORATORY MEASUREMENTS OF OZONE ISOTOPOMERS BY TUNABLE DIODE-LASER ABSORPTION-SPECTROSCOPY [J].
ANDERSON, SM ;
MORTON, J ;
MAUERSBERGER, K .
CHEMICAL PHYSICS LETTERS, 1989, 156 (2-3) :175-180
[3]   UPPER LIMIT ON THE RATE-CONSTANT FOR ISOTOPE EXCHANGE BETWEEN MOLECULAR-OXYGEN AND OZONE AT 298K [J].
ANDERSON, SM ;
MORTON, J ;
MAUERSBERGER, K .
GEOPHYSICAL RESEARCH LETTERS, 1987, 14 (12) :1258-1261
[4]  
ANDERSON SM, 1992, ACS S SERIES
[5]   ISOTOPIC FRACTIONATION IN THE FORMATION OF OZONE AND OF CARBON-DIOXIDE [J].
BATES, DR .
JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (12) :8739-8744
[6]   SUGGESTED EXPLANATION OF HEAVY OZONE [J].
BATES, DR .
GEOPHYSICAL RESEARCH LETTERS, 1988, 15 (01) :13-16
[7]   THE VAPOR-PRESSURES OF SOLID AND LIQUID OZONE [J].
HANSON, D ;
MAUERSBERGER, K .
JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (08) :4669-4672
[8]   A NON-MASS-DEPENDENT OXYGEN ISOTOPE EFFECT IN THE PRODUCTION OF OZONE FROM MOLECULAR-OXYGEN - THE ROLE OF MOLECULAR SYMMETRY IN ISOTOPE CHEMISTRY [J].
HEIDENREICH, JE ;
THIEMENS, MH .
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (04) :2129-2136
[9]   A NON-MASS-DEPENDENT ISOTOPE EFFECT IN THE PRODUCTION OF OZONE FROM MOLECULAR-OXYGEN [J].
HEIDENREICH, JE ;
THIEMENS, MH .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (02) :892-895
[10]   THE NON-MASS-DEPENDENT OXYGEN ISOTOPE EFFECT IN THE ELECTRODISSOCIATION OF CARBON-DIOXIDE - A STEP TOWARD UNDERSTANDING NOMAD CHEMISTRY [J].
HEIDENREICH, JE ;
THIEMENS, MH .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1985, 49 (06) :1303-1306