COMPLEX SALTS OF PLATINUM WITH ETHYLENEDIAMINE AND PROPANEDIAMINE [PTCL(DIAMINE)L][PTCL3L]

被引：6

作者：

FARRELL, N ^{[1
]}

DEALMEIDA, SG ^{[1
]}

QU, Y ^{[1
]}

机构：

[1] UNIV VERMONT,VERMONT REG CANC CTR,BURLINGTON,VT 05405

来源：

INORGANICA CHIMICA ACTA | 1990年 / 178卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)86783-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of anionic platinum salts K[PtCl3L], where L = NH3, DMSO or ethylene (C2H4) with the diamines ethylenediamine or 1,3-propanediamine in 2:1 stoichiometry gives as products the complex salts [PtCl3L][PtCl(diamine)L]. No evidence of complexes containing two platinum atoms linked by these short-chain diamines was found. The complex salts were characterised by H-1 and Pt-195 NMR spectroscopy.

引用

收藏

页码：209 / 211

页数：3

相关论文

共 18 条

[1] A CONVENIENT PREPARATION OF THE AMMINETRICHLORO-PLATINATE(II) ANION [J].

ABRAMS, MJ ;

GIANDOMENICO, CM ;

VOLLANO, JF ;

SCHWARTZ, DA .

INORGANICA CHIMICA ACTA, 1987, 131 (01) :3-4

[2]

BAILAR JC, 1973, COMP INORGANIC CHEM, V3, P1351

[3] NMR EVIDENCE FOR THERMODYNAMIC PREFERENCE OF CIS(N,OLEFIN) OVER TRANS(N,OLEFIN) ISOMERS OF MIXED AMINO-ACID OLEFIN COMPLEXES OF PLATINUM(II) [J].

ERICKSON, LE ;

BROWER, DC .

INORGANIC CHEMISTRY, 1982, 21 (02) :838-840

[4] CYTOTOXICITY AND ANTITUMOR-ACTIVITY OF BIS(PLATINUM) COMPLEXES - A NOVEL CLASS OF PLATINUM COMPLEXES ACTIVE IN CELL-LINES RESISTANT TO BOTH CISPLATIN AND 1,2-DIAMINOCYCLOHEXANE COMPLEXES [J].

FARRELL, N ;

QU, Y ;

HACKER, MP .

JOURNAL OF MEDICINAL CHEMISTRY, 1990, 33 (08) :2179-2184

[5] CHEMISTRY OF BIS(PLATINUM) COMPLEXES - FORMATION OF TRANS DERIVATIVES FROM TETRAAMINE COMPLEXES [J].

FARRELL, N ;

QU, Y .

INORGANIC CHEMISTRY, 1989, 28 (18) :3416-3420

[6]

FARRELL N, UNPUB INORG CHEM

[7] BIS(PLATINUM) COMPLEXES CONTAINING 2 PLATINUM CIS-DIAMMINE UNITS - SYNTHESIS AND INITIAL DNA-BINDING STUDIES [J].

FARRELL, NP ;

DEALMEIDA, SG ;

SKOV, KA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (15) :5018-5019

[8]

GELFMAN MI, 1970, ZH NEORG KHIM+, V15, P1438

[9] OLEFIN ROTATION IN PLATINUM(II) OLEFIN COMPLEXES .2. [J].

HOLLOWAY, CE ;

HULLEY, G ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (10) :1653-&

[10]

KUKUSHKIN YN, 1968, ZH NEORG KHIM+, V13, P835