A POLYMERIC TETRAIMINE SCHIFF-BASE MACROCYCLIC COMPLEX OF SILVER(I)

被引：9

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

FENTON, DE ^{[1
]}

HO, YS ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1993年 / 212卷 / 1-2期

关键词：

D O I：

10.1016/S0020-1693(00)92309-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I)-templated cyclocondensation of pyridine-2,6-dicarbaldehyde and 3-oxa-1,5-diaminopentane yields a dinuclear silver(I) complex of the '2+2' tetraimine Schiff base macrocycle L1. The crystal structure of the complex recrystallised from acetonitrile shows the product of recrystallisation to be polymeric with cyano-linked dimers being further associated through silver...silver interactions.

引用

页码：65 / 68

页数：4

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