STRUCTURE AND ORDERING IN METAL CYANIDE LATTICES - THE USE OF DOUBLY LABELED CYANIDE (C-13-N-15) TO SIMPLIFY THE C-13 MAS NMR-SPECTRUM

被引：21

作者：

CURTIS, RD

RATCLIFFE, CI

RIPMEESTER, JA

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,OTTAWA K1A 0R9,ONTARIO,CANADA

[2] NATL RES COUNCIL CANADA,INST BIOL SCI,OTTAWA K1A 0R9,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001800

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The relatively simple procedure of incorporating doubly labelled C-13-N-15 into metal cyanide' lattices gives a significant simplification of the MAS NMR spectrum, yielding readily interpretable structural information, and the first example of C-13-Cu-63, C-65 J coupling constants in the solid state, for NMe4Cu(I)Zn(CN)4.

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页码：1800 / 1802

页数：3

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