OPTICAL STUDY OF THE ELECTRONIC-STRUCTURE AND ELECTRON MOLECULAR VIBRATIONAL COUPLING IN A NOVEL ORGANIC SUPERCONDUCTOR KAPPA-(BEDT-TTF)2CU[N(CN)2]CL0.5BR0.5

被引:33
作者
DROZDOVA, OO [1 ]
SEMKIN, VN [1 ]
VLASOVA, RM [1 ]
KUSHCH, ND [1 ]
YAGUBSKII, EB [1 ]
机构
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
关键词
D O I
10.1016/0379-6779(94)90268-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Reflectance spectra of a new ambient-pressure superconductor, kappa-(BEDT-TTF)2Cu[N(CN)2]Cl0.5Br0.5 (T(c) = 11.3 K), where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene, are measured in the range from 750 to 5500 cm-1 and from 9000 to 40 000 cm-1 for different polarizations. The detailed analysis of the infrared conductivity, obtained after a Kramers-Kronig transformation, is performed in the framework of the approach, based on the 'phase phonons' theory of M.J. Rice, with the help of special transformation of the experimental data. Parameters of the electronic subsystem and electron-molecular vibration coupling are determined. The determined 'total' dimensionless coupling constant (lambda) is compared with those of the organic super conductors kappa-(BEDT-TTF)2Cu(NCS)2 (T(c) = 10.4 K) and (BEDT-TTF)4Hg2.89Br8 (T(c) = 4.3 K). It is found that a larger lambda produces a larger T(c) in accordance with the known Bardeen-Cooper-Schriffer formula for T(c).
引用
收藏
页码:17 / 26
页数:10
相关论文
共 33 条
  • [1] ALDOSHINA MZ, 1988, MATER SCI, V14, P45
  • [2] BELOUSOV MV, 1976, FIZ TVERD TELA+, V18, P2637
  • [3] BELOUSOV MV, 1978, FIZ TVERD TELA+, V20, P107
  • [4] POLARIZED OPTICAL REFLECTION SPECTRA OF HIGHLY ANISOTROPIC ORGANIC SEMICONDUCTOR TEA(TCNQ)2
    BRAU, A
    BRUESCH, P
    FARGES, JP
    HINZ, W
    KUSE, D
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1974, 62 (02): : 615 - 623
  • [5] BROUDE VL, 1981, SPEKTROSKOPIYA MOL E, P8
  • [6] INFRARED OPTICAL-PROPERTIES OF THE 12-K ORGANIC SUPERCONDUCTOR KAPPA-(BEDT-TTF)2CU[N(CN)2]BR
    ELDRIDGE, JE
    KORNELSEN, K
    WANG, HH
    WILLIAMS, JM
    CROUCH, AVS
    WATKINS, DM
    [J]. SOLID STATE COMMUNICATIONS, 1991, 79 (07) : 583 - 589
  • [7] EFFECTS OF CONFIGURATION INTERACTION ON INTENSITIES AND PHASE SHIFTS
    FANO, U
    [J]. PHYSICAL REVIEW, 1961, 124 (06): : 1866 - &
  • [8] INFRARED CONDUCTIVITY FROM SPIN AND CHARGE-DENSITY WAVES - (TMTSF)2X
    FENTON, EW
    PSALTAKIS, GC
    [J]. SOLID STATE COMMUNICATIONS, 1983, 47 (10) : 767 - 772
  • [9] STRAIN INDEX, LATTICE SOFTNESS AND SUPERCONDUCTIVITY OF ORGANIC DONOR-MOLECULE SALTS - CRYSTAL AND ELECTRONIC-STRUCTURES OF 3 ISOSTRUCTURAL SALTS KAPPA-(BEDT-TTF)2CU[N(CN)2]CL, KAPPA-(BEDT-TTF)2CU[N(CN)2]BR, KAPPA-(BEDT-TTF)2CU[N(CN)2]I
    GEISER, U
    SCHULTZ, AJ
    WANG, HH
    WATKINS, DM
    STUPKA, DL
    WILLIAMS, JM
    SCHIRBER, JE
    OVERMYER, DL
    JUNG, D
    NOVOA, JJ
    WHANGBO, MH
    [J]. PHYSICA C, 1991, 174 (4-6): : 475 - 486
  • [10] ISHIGURO T, 1990, SPRINGER SERIES SOLI, V88, P188