KETONES FROM CARBOXYLIC-ACIDS OVER SUPPORTED MAGNESIUM-OXIDE AND RELATED CATALYSTS

被引：40

作者：

SUGIYAMA, S ^{[1
]}

SATO, K ^{[1
]}

YAMASAKI, S ^{[1
]}

KAWASHIRO, K ^{[1
]}

HAYASHI, H ^{[1
]}

机构：

[1] KAO CORP,TOKYO RES LABS,TOKYO 131,JAPAN

来源：

CATALYSIS LETTERS | 1992年 / 14卷 / 01期

关键词：

ALKALINE EARTH CARBOXYLATES; KETONES; SUPPORTED MAGNESIA;

D O I：

10.1007/BF00764227

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica-supported alkaline earth oxides revealed excellent activity to convert acetic acid selectively into acetone in a vapor-phase fixed-bed flow system. Acetone was obtained through the cyclic formation of alkaline earth acetate followed by decomposition. Magnesium oxide should be supported on the silica surface without formation of magnesium silicate, which inactive for the present reaction. Attempted synthesis of benzophenone and acetophenone are also described.

引用

页码：127 / 133

页数：7

共 10 条

[1] HYDRAZINE SYNTHESIS BY A CATALYTIC-OXIDATION PROCESS [J].

HAYASHI, H .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1990, 32 (03) :229-277

[2] HYDRAZINE PRODUCTION FROM AMMONIA VIA AZINE [J].

HAYASHI, H ;

KAINOH, A ;

KATAYAMA, M ;

KAWASAKI, K ;

OKAZAKI, T .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1976, 15 (04) :299-303

[3] AMMONIA-HYDRAZINE CONVERSION PROCESSES .17. PREPARATION OF SULFONATED RESINS AS AN IMMOBILIZED PHASE-TRANSFER CATALYST FOR THE HYDROLYSIS OF BENZOPHENONE AZINE TO HYDRAZINE [J].

HAYASHI, H ;

SOMEI, J ;

AKEI, M ;

SUGA, T ;

KIGAMI, H ;

HIRAMATSU, N ;

ITOYAMA, H ;

NAKANO, T ;

OKAZAKI, T .

JOURNAL OF CATALYSIS, 1991, 130 (02) :547-555

[4] CHEMICAL UTILIZATION OF HYDRAZINE DERIVATIVES .1. CATALYSTS FOR VAPOR-PHASE FISCHER INDOLE SYNTHESIS [J].

HAYASHI, H ;

KUROKAWA, K ;

HOSOKAWA, W ;

TANAKA, T ;

OKAZAKI, T .

JOURNAL OF CATALYSIS, 1980, 66 (01) :49-55

[5]

KRONIG W, 1924, Z ANGEW CHEM, V37, P667

[6]

LANGE NA, 1961, HDB CHEM, P266

[7]

Sabatier P, 1914, CR HEBD ACAD SCI, V158, P830

[8]

Sabatier P., 1920, CATALYSE CHIMIE ORGA, DOI DOI 10.14375/NP.9782369430186

[9]

SQUIBB RE, 1896, J AM CHEM SOC, V18, P231

[10]

SQUIBB RE, 1895, J AM CHEM SOC, V17, P187

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