UNUSUAL BEHAVIOR OF SOME GAMMA-LACTONES AND DELTA-LACTONES TOWARDS DICHLOROMETHYLENATION USING TRIS(DIMETHYLAMINO)PHOSPHINE-TETRACHLOROMETHANE

被引：17

作者：

BANDZOUZI, A ^{[1
]}

LAKHRISSI, M ^{[1
]}

CHAPLEUR, Y ^{[1
]}

机构：

[1] UNIV NANCY 1,CHIM ORGAN LAB 3,CNRS,UA 486,BP 239,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 12期

关键词：

D O I：

10.1039/p19920001471

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lactones derived from D-glucose, D-mannose and L-ascorbic acid reacted unexpectedly with tris-(dimethylamino)phosphine-tetrachloromethane to give, respectively, dichloroalkene, anomeric vinyl chloride or acyl chloride; this behaviour supports an ionic mechanism for the alkenation.

引用

页码：1471 / 1473

页数：3

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