SYNTHESIS AND STRUCTURE OF A SILYL-AMINOALANE RING

被引：10

作者：

JANIK, JF

DUESLER, EN

PAINE, RT

机构：

[1] UNIV NEW MEXICO,DEPT CHEM,ALBUQUERQUE,NM 87131

[2] UNIV MIN & MET KRAKOW,AGH,PL-30059 KRAKOW,POLAND

来源：

CHEMISCHE BERICHTE | 1993年 / 126卷 / 12期

关键词：

ALANE; AMINO-; ALUMINUM NITRIDE;

D O I：

10.1002/cber.19931261213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of hydrazine with tris(trimethylsilyl)aluminium-ether have been studied: Reactant ratios of 0.5:1 and 0.8:1 produce the cyclic aminoalane [(Me(3)Si)(2)AlN(H)(SiMe(3))](2) (1), which is formed by N-N bond cleavage and silyl group migration from aluminium to nitrogen. Pyrolysis under NH3 of a polymeric product formed from a 1:1 reaction produces an AlN/Si3N4 composite.

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页码：2649 / 2651

页数：3

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