BIS-FUNCTIONALIZATION OF C-60 VIA THERMAL REARRANGEMENT OF AN ISOLABLE FULLEROAZIRIDINE BEARING A SOLUBILIZING SUPERMESITYL ESTER MOIETY

被引：67

作者：

BANKS, MR

CADOGAN, JIG

GOSNEY, I

HODGSON, PKG

LANGRIDGESMITH, PRR

RANKIN, DWH

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL, DEPT CHEM, LONDON SW7 2AY, ENGLAND

[2] BP INT LTD, CTR RES & ENGN, SUNBURY TW16 7LN, MIDDX, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heating of C-60 with the novel azidoformate 3 bearing a highly solubilising supermesityl group affords the first example of a nitrogen-bridged fullerene 4 with a sigma-homoaromatic closed 6,6-aziridine structure, which by further heating can be induced to undergo rearrangement on the fullerene surface to form as the sole product, the closed isomeric oxazole derivative 5 with O and N vicinally bound to the fullerene framework at a 6,6-ring juncture

引用

页码：1365 / 1366

页数：2

共 17 条

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