AZIRIDINATION OF ALKENES USING 3-ACETOXYAMINOQUINAZOLIN-4-(3H)ONES IN THE PRESENCE OF TERTIARY-AMINES - EVIDENCE FOR AN AZAIMIDE (N-NITRENE) INTERMEDIATE

被引：16

作者：

ATKINSON, RS

BARKER, E

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000819

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solutions of the triethylammonium imide 8, formed from triethylamine and 3-acetoxyaminoquinazolinone 4, react with alkenes at -30 degrees C to give aziridines; the reactivity of the aziridinating intermediate is consistent with its formulation as an azaimide (N-nitrene).

引用

页码：819 / 820

页数：2