SIO2-GRAFTED DINUCLEAR MOLYBDENUM CATALYST DERIVED FROM MO2(OAC)4 - HIGHLY-ACTIVE FOR ALKENE METATHESIS REACTION

被引：26

作者：

ZHUANG, Q ^{[1
]}

FUKUOKA, A ^{[1
]}

FUJIMOTO, T ^{[1
]}

TANAKA, K ^{[1
]}

ICHIKAWA, M ^{[1
]}

机构：

[1] HOKKAIDO UNIV,CATALYSIS RES CTR,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 11期

关键词：

D O I：

10.1039/c39910000745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SiO2-grafted dinuclear molybdenum species derived from Mo2(OAc)4, e.g. [Mo = Mo]v, which are characterized by ESR and EXAFS spectroscopy, exhibit marked catalytic activity for propene metathesis reaction, but are inactive for ethene homologation.

引用

页码：745 / 746

页数：2

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