MATHEMATICAL-ANALYSIS OF REACTIVE ION-TRANSPORT IN DYNAMIC EQUILIBRIUM - THE CASE OF 2 IONIC SPECIES

被引：5

作者：

IINUMA, K

TAKEBE, M

机构：

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 06期

关键词：

D O I：

10.1139/v92-198

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An exact solution for the transport of two reacting ion species in a drift tube is developed. The calculation of the temporal variation of ion fluxes is simplified using an approximate formulation in terms of the reaction frequencies, drift velocities, and longitudinal diffusion coefficients. The exact and approximate formulations are compared for the case of (N2+, N4+)/N2 with a view to establishing the approach to equilibrium.

引用

页码：1604 / 1611

页数：8

共 16 条

[1]

[Anonymous], 1988, NASA STI RECON TECHN

[2]

BOHRINGER H, 1982, J CHEM PHYS, V77, P5534, DOI 10.1063/1.443758

[3] STUDIES OF ION MOLECULE REACTIONS, ION MOBILITIES, AND THEIR TEMPERATURE-DEPENDENCE TO VERY LOW-TEMPERATURES USING A LIQUID-HELIUM-COOLED ION DRIFT TUBE [J].