ON THE OXIDATION OF 3-ETHYLPENTANE UNDER GIF(IV) AND GIF(ORSAY) CONDITIONS

被引：8

作者：

BARTON, DHR

DOLLER, D

OZBALIK, N

BALAVOINE, G

GREF, A

BOIVIN, J

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CNRS,LA 225,F-91405 ORSAY,FRANCE

[2] ECOLE POLYTECH,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(00)94553-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of 3-ethylpentane under GifIV (and GoAggII) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously reported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary CH bond. © 1990.

引用

页码：353 / 356

页数：4

共 14 条

[1] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .10. A COMPARATIVE-STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES [J].