SELECTIVE FUNCTIONALIZATION OF CALIX[4]ARENES AT THE UPPER RIM

被引：371

作者：

VANLOON, JD

ARDUINI, A

COPPI, L

VERBOOM, W

POCHINI, A

UNGARO, R

HARKEMA, S

REINHOUDT, DN

机构：

[1] UNIV PARMA,INST ORGAN CHEM,I-43100 PARMA,ITALY

[2] TWENTE UNIV TECHNOL,ORGAN CHEM LAB,7500 AE ENSCHEDE,NETHERLANDS

[3] TWENTE UNIV TECHNOL,CHEM PHYS LAB,7500 AE ENSCHEDE,NETHERLANDS

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 21期

关键词：

D O I：

10.1021/jo00308a024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methods are described for the selective diametrical functionalization of calix[4]arenes at the upper rim, either by the selective removal of the p-tert-butyl groups and subsequent substitution at the free phenol rings or by selective reactions at the phenol rings of dialkoxycalix[4]arenes without the tert-butyl groups. This includes selective mercuration and the synthesis of 5,17-di-£erf-butyl-26,28-dimethoxy-ll,23-diphenylcalix[4]arene (13), of which the crystal structure is described. The first synthesis of macrocyclic diquinones derived from calix[4]arenes (calix[4]diquinones) is described. © 1990, American Chemical Society. All rights reserved.

引用

页码：5639 / 5646

页数：8

共 37 条

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