SHORT AND EFFICIENT SYNTHESES OF (-)-ISOCITRIC ACID LACTONE AND (-)-HOMOISOCITRIC ACID - CONVERSION OF ALKYNYLSILANES INTO THE CORRESPONDING CARBOXYLIC-ACIDS

被引：3

作者：

SCHMITZ, C ^{[1
]}

ROUANETDREYFUSS, AC ^{[1
]}

TUENI, M ^{[1
]}

BIELLMANN, JF ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST CHIM,CNRS,CHIM ORGAN BIOL LAB,1 RUE BLAISE PASCAL,F-67008 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 34期

关键词：

ISOCITRIC ACID LACTONE; HOMOISOCITRIC ACID; D-MALIC ACID; CONVERSION OF ALKYNYLSILANE TO CARBOXYLIC ACID;

D O I：

10.1016/S0040-4039(00)61231-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe a simple synthesis of natural isocitric and homoisocitric acids from a common intermediate 2. A new method of conversion from a silylated triple bond to the carboxylic acid of the same chain length has been formulated.

引用

页码：4911 / 4912

页数：2

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