SILVER(I) COMPLEXES WITH HETEROCYCLIC THIONES AND TRIPHENYLPHOSPHINE AS LIGANDS - THE CRYSTAL-STRUCTURE OF SILVER(I) PYRIDINE-2-THIONE BIS(TRIPHENYLPHOSPHINE) CHLORIDE [AG(PPH3)2(PY2SH)CL]

被引：37

作者：

KARAGIANNIDIS, P ^{[1
]}

ASLANIDIS, P ^{[1
]}

KOKKOU, S ^{[1
]}

CHEER, CJ ^{[1
]}

机构：

[1] ARISTOTELIAN UNIV SALONIKA,APPL PHYS LAB,GR-54006 SALONIKA,GREECE

来源：

INORGANICA CHIMICA ACTA | 1990年 / 172卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80863-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex formation between [Ag(PPh3)Cl]4 and heterocyclic thiones (L) [L=pyridine-2-thione (py2SH), pyridine-4-thione (py4SH), pyrimidine-2- thione (pymtH), 1,3-thiazolidine-2-thione (tzdtH), 1-methyl-1,3-imidazoline-2-thione (meimtH), benz- 1,3-thiazoline-2-thione (bztzH), benz-1,3-imidazoline- 2-thione (bzimtH2), 5-nitro-2-benz-1,3-imidazoline-2- thione (nbzimtH2) and quinazolinone-2-thione (qnotH2)] has been investigated. The infrared spectral data suggest the formation of mononuclear complexes of the general formula [Ag(PPh3)2(L)Cl] in which the thione ligands behave as monodentate, coordination occurring through the S atom. The crystal structure of the pyridine-2-thione complex has been determined by single-crystal X-ray diffraction methods. The yellow crystals are monoclinic, space group P21/c with a=14.362(2), b=10.302(1), c=25.054(3) Å, β=93.38(1)°, Dcalc=1.398 Mg m-3, V=3700.3 Å3 and Z=4. © 1990.

引用

页码：247 / 251

页数：5

共 28 条

[1] STRUCTURAL STUDIES OF STERIC EFFECTS IN PHOSPHINE COMPLEXES .10. CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(TRIMESITYLPHOSPHINE)SILVER(I) HEXAFLUOROPHOSPHATE [J].

ALYEA, EC ;

FERGUSON, G ;

SOMOGYVARI, A .

INORGANIC CHEMISTRY, 1982, 21 (04) :1369-1371

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] SILVER(I) COMPLEXES OF "4,6-DIMETHYLPYRIMIDINE-2(1H)-THIONE [J].

BATTISTUZZI, R ;

PEYRONEL, G .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1981, 59 (03) :591-596

[4] CORRELATION BETWEEN P-31 NMR DATA AND STRUCTURAL PARAMETERS ON AG(PPH3)3X SERIES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRIS(TRIPHENYLPHOSPHINE)SILVER(I)TETRAFLUOROBORATE AND TRIS(TRIPHENYLPHOSPHINE)SILVER(I)IODIDE [J].

CAMALLI, M ;

CARUSO, F .

INORGANICA CHIMICA ACTA, 1987, 127 (02) :209-213

[5] METAL-COMPLEXES AS LIGANDS .4. STRUCTURES OF BIS[BIS(TRIPHENYLPHOSPHINE)SILVER(I)] BIS(1,2-DICYANO-1,2-ETHYLENEDITHIOLATO)NICKELATE(II), [AG(P(C6H5)3)2]2NI(S2C2(CN)2)2, AND OF BIS[BIS(TRIPHENYLPHOSPHINE)SILVER(I)] BIS(1,1-DICYANO-2,2-ETHYLENEDITHIOLATO)NICKELATE(II), [AG(P(C6H5)3)2]2NI(S2C=C(CN)2)2 [J].

COUCOUVANIS, D ;

BAENZIGER, NC ;

JOHNSON, SM .

INORGANIC CHEMISTRY, 1974, 13 (05) :1191-1199

[6] ANTI-TUMOUR ACTIVITY OF HEAVY TRANSITION-METAL COMPLEXES AGAINST HEPATOMA-CELLS [J].

DEHAND, J ;

JORDANOV, J ;

BECK, JP .

CHEMICO-BIOLOGICAL INTERACTIONS, 1975, 11 (06) :605-609

[7] LEWIS-BASE ADDUCTS OF GROUP-11 METAL(I) COMPOUNDS .30. 3-1 COMPLEXES OF TRIPHENYLPHOSPHINE WITH SILVER(I) HALIDES [J].

ENGELHARDT, LM ;

HEALY, PC ;

PATRICK, VA ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (11) :1873-1880

[8] SYNTHESIS AND ANTI-TUMOR ACTIVITY OF PLATINUM COMPLEXES WITH CYCLIC THIOAMIDES [J].

FUJIEDA, S ;

TABATA, E ;

HATANO, A ;

OSA, T .

HETEROCYCLES, 1981, 15 (02) :743-746

[9] THE STRUCTURE OF A DINUCLEAR SILVER(I) COMPLEX - AG2[S2C2(CN)2][P(C6H5)3]4 [J].

HEINRICH, DD ;

FACKLER, JP ;

LAHUERTA, P .

INORGANICA CHIMICA ACTA, 1986, 116 (01) :15-19

[10] METAL-COMPLEXES AS LIGANDS .5. CRYSTAL AND MOLECULAR-STRUCTURES OF TRIS(BIS(TRIPHENYLPHOSPHINE)SILVER(I)) TRIS(DITHIOOXALATO)IRON(III) AND -ALUMINUM(III), [AG(P(C6H5)3)2]3M(O2C2S2)3, M = FE(III) AND AL(III) [J].

HOLLANDE.FJ ;

COUCOUVA.D .

INORGANIC CHEMISTRY, 1974, 13 (10) :2381-2386

← 1 2 3 →