CHEMISTRY OF ETHANEDIYL S,S-ACETALS .7. A STEREOSELECTIVE SYNTHESIS OF ALLYLIC ALCOHOLS WITH CIS-CONFIGURATED DOUBLE-BOND

被引：5

作者：

CAPUTO, R ^{[1
]}

FERRERI, C ^{[1
]}

LONGOBARDO, L ^{[1
]}

MASTROIANNI, D ^{[1
]}

PALUMBO, G ^{[1
]}

PEDATELLA, S ^{[1
]}

机构：

[1] UNIV NAPOLI FEDERICO 2,DIPARTIMENTO CHIM ORGAN & BIOL,VIA MEZZOCANNONE 16,I-80134 NAPLES,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 09期

关键词：

D O I：

10.1080/00397919408011721

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new high yielding coupling reaction of C-2 monosubstituted 5,6-dihydro-1,4-dithiins with aldehydes is reported. In this way allylic alcohols having the cis-substituted double bond tied up by a sulfur-containing ring can be readily prepared. Subsequent stereoselective sulfur removal then affords allylic alcohols with cis-configurated double bond.

引用

页码：1223 / 1229

页数：7

共 8 条

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