THE VIBRATIONAL DEPENDENCE OF THE DIPOLE-MOMENT OF HYDROGEN-FLUORIDE

被引：8

作者：

BARNES, JA ^{[1
]}

GOUGH, TE ^{[1
]}

STOER, M ^{[1
]}

机构：

[1] UNIV VICTORIA,DEPT CHEM,VICTORIA V8W 3P6,BC,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1994年 / 72卷 / 03期

关键词：

D O I：

10.1139/v94-072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular beam laser Stark spectroscopy has been used to measure the v = 3 vibrational state dipole moment of hydrogen fluoride as 1.9614 +/- 0.0021 debye. This measurement allows mu(v) to be expressed as a power series expansion in (v + 1/2) without the use of infrared intensity data. A detailed comparison is made with similar series based mainly on infrared intensity data and more recent ab initio calculations.

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页码：499 / 505

页数：7

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