ACID-BASE CONTRIBUTIONS TO POLYMER-FILLER INTERACTIONS

被引：52

作者：

FOWKES, FM

机构：

来源：

RUBBER CHEMISTRY AND TECHNOLOGY | 1984年 / 57卷 / 02期

关键词：

CHLORINE CONTAINING POLYMERS - Fillers;

D O I：

10.5254/1.3536012

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The author studied the adsorption of poly(methylmethacrylate) and chlorinated poly(vinyl chloride) onto an acidic filler (silica) and a basic filler (calcium carbonate) from solutions in a neutral solvent (carbon tetrachloride), in two acidic solvent (methylene chloride and chloroform), and in three basic solvent (benzene, p-dioxane and tetrahydrofuran. Acid-base interactions are shown to determine adsorption and bonding of polymers to fillers. Acid-base interactions between polymers and fillers generate high zeta-potentials which tend to eliminate filler flocculation and reduce viscosity of filled polymer melts.

引用

页码：328 / 343

页数：16

共 31 条

[1] ACIDITY OF CATALYST SURFACES .2. AMINE TITRATION USING HAMMETT INDICATORS
BENESI, HA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1957, 61 (07) : 970 - 973
[2] FORCES INVOLVED IN ADHESIVE PROCESS .1. CRITICAL SURFACE TENSIONS OFPOLYMERIC SOLIDS AS DETERMINED WITH POLAR LIQUIDS
DANN, JR
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 32 (02) : 302 - &
[3] FORCES INVOLVED IN ADHESIVE PROCESS .2. NONDISPERSION FORCES AT SOLID-LIQUID INTERFACES
DANN, JR
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 32 (02) : 321 - &
[4] 4-PARAMETER EQUATION FOR PREDICTING ENTHALPIES OF ADDUCT FORMATION
DRAGO, RS
VOGEL, GC
NEEDHAM, TE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (23) : 6014 - &
[5] SOLVENT EFFECTS AND THEIR RELATIONSHIP TO E AND C EQUATION
DRAGO, RS
PARR, LB
CHAMBERLAIN, CS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (10) : 3203 - 3209
[6] Fowkes F. M., 1977, COATINGS PLASTICS PR, V37, P605
[7] DETERMINATION OF INTERFACIAL TENSIONS, CONTACT ANGLES, AND DISPERSION FORCES IN SURFACES BY ASSUMING ADDITIVITY OF INTERMOLECULAR INTERACTIONS IN SURFACES
FOWKES, FM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (02) : 382 - &
[8] FOWKES FM, 1982, ACS SYM SER, V200, P307
[9] ATTRACTIVE FORCES AT INTERFACES
FOWKES, FM
[J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1964, 56 (12): : 40 - &
[10] ACID-BASE INTERACTIONS IN POLYMER ADSORPTION
FOWKES, FM
MOSTAFA, MA
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1978, 17 (01): : 3 - 7

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