ENHANCEMENT EFFECT OF PENTAFLUOROPHENOL ON THE LIQUID-LIQUID PARTITION OF TRIS(ACETYLACETONATO) COMPLEXES OF CHROMIUM(III) AND COBALT(III)

被引：9

作者：

KATSUTA, S ^{[1
]}

IMURA, H ^{[1
]}

SUZUKI, N ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.733

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The partition coefficient of tris(acetylacetonato)-chromium(III) and -cobalt(III) (M(acac)3) between heptane and aqueous solutions was remarkably enhanced by the presence of pentafluorophenol (PFP). This effect was ascribed to the formation of the hydrogen-bonded association complexes, M(acac)3 . PFP and M(acac)3 . 2PFP, in the organic phase, and the association constants were determined.

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页码：733 / 736

页数：4

相关论文

共 8 条

[1] LIQUID-LIQUID PARTITION OF TRIS-(ACETYLACETONATO) METAL(III) COMPLEXES IN HEPTANE-WATER DIMETHYL SULFOXIDE MIXTURE SYSTEMS [J].

AWANO, H ;

WATARAI, H ;

SUZUKI, N .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1979, 41 (01) :124-126

[2] ELECTRONIC ABSORPTION SPECTRA OF ACETYL-ACETONATO COMPLEXES .1. COMPLEXES WITH TRIVALENT TRANSITION METAL IONS [J].

BARNUM, DW .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 21 (3-4) :221-237

[3] SOLVENT EFFECT ON THE LIQUID LIQUID PARTITION-COEFFICIENTS OF DIMETHYLDITHIOCARBAMIC ACID AND ITS COPPER(II) CHELATE [J].

IMURA, H ;

MATSUMORA, S ;

SUZUKI, N .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (02) :621-626

[4] SOLVENT EFFECT ON THE LIQUID LIQUID PARTITION-COEFFICIENTS OF COPPER(II) CHELATES WITH SOME BETA-DIKETONES [J].

IMURA, H ;

SUZUKI, N .

TALANTA, 1985, 32 (8B) :785-790

[5] UNCOUPLERS OF RAT-LIVER MITOCHONDRIAL OXIDATIVE PHOSPHORYLATION [J].

PARKER, VH .

BIOCHEMICAL JOURNAL, 1965, 97 (03) :658-+

[6] PROTON MAGNETIC RESONANCE CHEMICAL SHIFT OF FREE (GASEOUS) AND ASSOCIATED (LIQUID) HYDRIDE MOLECULES [J].

SCHNEIDER, WG ;

BERNSTEIN, HJ ;

POPLE, JA .

JOURNAL OF CHEMICAL PHYSICS, 1958, 28 (04) :601-607

[7] DETERMINATION OF PARTITION-COEFFICIENTS OF HALOBENZENES IN HEPTANE WATER AND 1-OCTANOL WATER-SYSTEMS AND COMPARISON WITH THE SCALED PARTICLE CALCULATION [J].

WATARAI, H ;

TANAKA, M ;

SUZUKI, N .

ANALYTICAL CHEMISTRY, 1982, 54 (04) :702-705

[8]

WATARAI H, 1984, QUANT STRUCT-ACT REL, V3, P17