SOLID-STATE EFFECT ON THE PHOSPHORESCENCE SPECTRUM OF A TRIS(3,3'-BIISOQUINOLINE)RUTHENIUM(II) SALT

被引：11

作者：

KATO, M ^{[1
]}

SASANO, K ^{[1
]}

KIMURA, M ^{[1
]}

YAMAUCHI, S ^{[1
]}

机构：

[1] TOHOKU UNIV, INST CHEM REACT SCI, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.1887

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A broad and red-shifted emission spectrum was observed in the neat crystal of [Ru(i-biq)3](PF6)2 (i-biq = 3,3'-biisoquinoline) in contrast to a sharp 3pipi*-type emission spectrum in a dilute glassy solution. On the basis of the analyses of the concentration dependence of the emission spectrum and the X-ray crystal structure, the characteristic emission of the crystal was attributed to pi-pi interactions between the i-biq ligands of the adjacent complexes.

引用

页码：1887 / 1890

页数：4

共 8 条

[1] SYNTHESIS, SPECTROSCOPIC DATA AND ELECTROCHEMICAL-BEHAVIOR OF RUTHENIUM(II) COMPLEXES WITH BIDENTATE LIGANDS [J].

BELSER, P ;

ZELEWSKY, AV .

HELVETICA CHIMICA ACTA, 1980, 63 (06) :1675-1702

[2] LIGAND-CENTERED LUMINESCENCE FROM A RUTHENIUM(II) COMPLEX [J].

BELSER, P ;

VONZELEWSKY, A ;

JURIS, A ;

BARIGELLETTI, F ;

TUCCI, A ;

BALZANI, V .

CHEMICAL PHYSICS LETTERS, 1982, 89 (02) :101-104

[3]

BELSER P, 1985, GAZZ CHIM ITAL, V115, P723

[4] CIS-TRANS PHOTOISOMERIZATION IN RU(BPY)2(OH2)22+ - CRYSTAL-STRUCTURE OF TRANS-[RU(BPY)2(OH2)(OH)](CLO4)2 [J].

DURHAM, B ;

WILSON, SR ;

HODGSON, DJ ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :600-607

[5] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE [J].

JURIS, A ;

BALZANI, V ;

BARIGELLETTI, F ;

CAMPAGNA, S ;

BELSER, P ;

VONZELEWSKY, A .

COORDINATION CHEMISTRY REVIEWS, 1988, 84 :85-277

[6] ELECTRONIC-SPECTRA AND PHOTOPHYSICS OF PLATINUM(II) COMPLEXES WITH ALPHA-DIIMINE LIGANDS - SOLID-STATE EFFECTS .1. MONOMERS AND LIGAND PI-DIMERS [J].

MISKOWSKI, VM ;

HOULDING, VH .

INORGANIC CHEMISTRY, 1989, 28 (08) :1529-1533

[7] STRUCTURE OF TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) HEXAFLUOROPHOSPHATE, [RU(BIPY)3][PF6]2 - X-RAY CRYSTALLOGRAPHIC DETERMINATION [J].

RILLEMA, DP ;

JONES, DS ;

LEVY, HA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (19) :849-851

[8]

SAKURAI T, 1979, RIKAGAKU KENKYUSHO H, V55, P69

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