ELECTROCHEMICAL STUDIES ON ORGANOMETALLIC COMPOUNDS .41. ELECTROGENERATION AND ESR CHARACTERIZATION OF [NB(ETA-5-C5H4SIME3)2CL(P(OME)3)]+

被引：12

作者：

LUCAS, D

MUGNIER, Y

ANTINOLO, A

OTERO, A

FAJARDO, M

机构：

[1] FAC SCI DIJON, CNRS,SYNTH & ELECTROSYNTH ORGANOMET LAB,URA 33, 6 BD GABRIEL, F-21000 DIJON, FRANCE

[2] UNIV CASTILLA LA MANCHA, DEPT QUIM INORGAN, E-13071 CIUDAD REAL, SPAIN

[3] UNIV ALCALA DE HENARES, DEPT QUIM INORGAN, E-28871 ALCALA DE HENARES, SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 435卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83407-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In tetrahydrofuran with 0.2 M NaBPh4 as supporting electrolyte, the one-electron oxidation at -0.4 V relative to an aqueous saturated calomel electrode (SCE) of the electrogenetated species [Nb(eta-5-C5H4SiMe3)2{CIP(OMe)3}] (3) yields the cationic niobium(IV) complex [Nb(eta-5-C5H4SiMe3)2-Cl{P(OMe)3}]+ (4), which has been characterized by ESR spectroscopy. 4 can also be obtained by chemical oxidation of 3.

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页码：C3 / C7

页数：5

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