HIGH-PRESSURE NITRATION OF TOLUENE USING NITROGEN-DIOXIDE ON ZEOLITE CATALYSTS

被引：25

作者：

AKOLEKAR, DB ^{[1
]}

LEMAY, G ^{[1
]}

SAYARI, A ^{[1
]}

KALIAGUINE, S ^{[1
]}

机构：

[1] UNIV LAVAL,CERPIC,QUEBEC CITY,PQ G1K 7P4,CANADA

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1995年 / 21卷 / 01期

关键词：

D O I：

10.1163/156856795X00026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitration of toluene by nitrogen dioxide in the presence of zeolite catalysts was carried out in a high pressure reaction system. Different zeolites (viz. H-ZSM-5, H-mordenite, HY etc.) were used as catalysts. The effects of NO2/toluene molar ratio and the total pressure on the formation of mono- and di-nitrotoluenes were also investigated. The N-2-sorption capacity, X-ray diffraction analysis and catalytic activity measurements of the regenerated HY catalyst revealed that the HY catalyst can be reused.

引用

页码：7 / 16

页数：10

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