MULTIFRACTALITY OF LYOTROPIC LIQUID-CRYSTAL FORMATION OF ALUMINUM DODECYLBENZENESULPHONATE

被引:11
作者
TEZAK, D
MARTINIS, M
PUNCEC, S
FISCHERPALKOVIC, I
STRAJNAR, F
机构
[1] Department of Chemistry, University of Zagreb, Zagreb, HR-41001, Marulićev trg 19
[2] ‘Rugjer Boskovic’ Institute, Zagreb, HR-41001
关键词
D O I
10.1080/02678299508031965
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The formation of colloidal and liquid crystalline aggregates of aluminium dodecylbenzene-sulphonate caused by mixing aqueous solutions of Al(NO3)(3) and dodecylbenzenesulphonic acid (HDBS) was investigated by light scattering and polarizing microscopy. Applying a fractal approach, some aggregates can be considered as multifractals and some as fractals, depending on the slopes of the 'lgI(Q) versus lg Q' plots (for multifractals the slopes are > 3). A model of multiscaling for the calculation of fractal dimensions in the formation of the liquid crystalline phases is proposed, describing both the spacial and the temporal dependence of amphiphile self-aggregation. The basic symmetries of the dynamics of formation and the structures of the liquid crystalline phases were found to be consistent.
引用
收藏
页码:159 / 167
页数:9
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