PERMANGANATE MALONIC-ACID INITIATED POLYMERIZATION OF ACRYLAMIDE AND METHACRYLAMIDE

被引：8

作者：

BEHARI, K

GUPTA, KC

RAJA, GD

DAS, P

机构：

[1] University of Allahabad, Department of Chemistry, Polymer Laboratory, Allahabad

[2] Department of Chemistry, University of Roorkee, Roorkee

来源：

ACTA POLYMERICA | 1991年 / 42卷 / 05期

关键词：

D O I：

10.1002/actp.1991.010420504

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetics of aqueous polymerization of acrylamide and methyacrylamide using the redox pair potassium permanganate and malonic acid was studied. It was found that the order of the polymerization reaction is 0.5 with respect to permanganate and malonic acid, respectively, and 1.0 with respect to the concentration of the monomers. Polymer samples were prepared under different conditions, and their viscosity average molecular weights were determined. A plausible mechanism for the explanation of the experimental results is proposed.

引用

页码：206 / 210

页数：5

共 26 条

[1] KINETICS OF VINYL POLYMERIZATION INITIATED BY POTASSIUM-PERMANGANATE BETA-HYDROXYBUTYRIC ACID REDOX SYSTEM [J].

BEHARI, K ;

GUPTA, KC ;

VERMA, M .

ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1985, 130 (MAR) :67-80

[2]

BEHARI K, 1984, COLLOID POLYM SCI, V262

[3]

BEHARI K, 1986, MACROMOLECULES, V19, P548

[4]

BISWAS M, 1961, J SCI IND RES B PH S, V20, P160

[5] STAGES IN OXIDATIONS OF ORGANIC COMPOUNDS BY POTASSIUM PERMANGANATE .4. OXIDATION OF MALONIC ACID AND ITS ANALOGUES [J].

DRUMMOND, AY ;

WATERS, WA .

JOURNAL OF THE CHEMICAL SOCIETY, 1954, (JUL) :2456-2467

[6]

GANGA DN, 1972, MAKROMOL CHEM, V152, P177

[7]

JAKAY M, 1972, J CHEM SOC P2, P2326

[8]

JAKAY M, 1972, J CHEM SOC P2, P1481

[9]

JAKAY M, 1973, J CHEM SOC P2, P1565

[10]

JOSEFOWITZ D, 1945, POLYM B, V1, P140

← 1 2 3 →