DI-MU-CHLORO-BIS[CIS,CIS-ETA(4)-1,5-CYCLOOCTADIENE)RHODIUM(I)] - A REDETERMINATION

被引：22

作者：

DERIDDER, DJA

IMHOFF, P

机构：

[1] UNIV AMSTERDAM,KRISTALLOG LAB,1018 WV AMSTERDAM,NETHERLANDS

[2] UNIV AMSTERDAM,ANORGAN CHEM LAB,1018 WV AMSTERDAM,NETHERLANDS

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194001459

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of [Rh2Cl2(C8H12)2] has been redetermined. The precision of this structure determination compared with other published data shows an improvement such that averaged bond distance and angle e.s.d.'s are smaller by a factor of two. The bond distances in the cis,cis-1,5-cyclooctadiene ring are compared to those of analogous compounds in the Cambridge Structural Database. The title compound has no molecular symmetry; the cis,cis-1,5-cyclooctadiene rings each have a boat conformation showing C2nu symmetry.

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页码：1569 / 1572

页数：4

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