NON-TWISTED TETRAKIS(ORGANOSILYL)ETHENE

被引：37

作者：

MURAKAMI, M ^{[1
]}

SUGINOME, M ^{[1
]}

FUJIMOTO, K ^{[1
]}

ITO, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM,KYOTO 60601,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 10期

关键词：

D O I：

10.1002/anie.199314731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular bissilylation under high pressure yields the ethene derivative 1, whose structure is not twisted about the CC bond. Its UV spectra and crystal structure suggests that the weak absorption at 361 nm is attributable to the fourfold Si substitution and not, as previously suggested for tetrakis(organosilyl)ethenes, from twisting. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1473 / 1475

页数：3

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