OXIDATION OF ACTIVATED PHENOLS BY DIOXYGEN CATALYZED BY THE H5PV2MO10O40 HETEROPOLYANION

被引：73

作者：

LISSEL, M ^{[1
]}

DEWAL, HJI ^{[1
]}

NEUMANN, R ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,GRAD SCH APPL SCI & TECHNOL,CASALI INST APPL CHEM,IL-91904 JERUSALEM,ISRAEL

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 13期

关键词：

HETEROPOLYANIONS; PHENOL OXIDATION; DIOXYGEN;

D O I：

10.1016/S0040-4039(00)91735-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.

引用

页码：1795 / 1798

页数：4

共 27 条

[1] AUBRY C, 1990, 4TH INT S ACT DIOX C
[2] OXIDATION OF ALKYNES CATALYZED BY MO(VI) AND W(VI) POLYOXOMETALATES
BALLISTRERI, FP
FAILLA, S
SPINA, E
TOMASELLI, GA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (04) : 947 - 949
[3] DAUMAS M, 1989, SYNTHESIS-STUTTGART, P64
[4] ELALI B, 1989, NEW J CHEM, V13, P173
[5] THE OXIDATION OF KETONES WITH A HETEROPOLYACID, H5[PMO10V2O40] AND DIOXYGEN
ELALI, B
BREGEAULT, JM
MERCIER, J
MARTIN, J
MARTIN, C
CONVERT, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (13) : 825 - 826
[6] POLYMERIZATION BY OXIDATIVE COUPLING . FUNCTION OF COPPER IN OXIDATION OF 2,6-DIMETHYLPHENOL
FINKBEIN.H
HAY, AS
BLANCHAR.HS
ENDRES, GF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (02) : 549 - &
[7] PHOTOACTIVATION OF METAL-OXIDE SURFACES - PHOTOCATALYZED OXIDATION OF ALCOHOLS BY HETEROPOLYTUNGSTATES
FOX, MA
CARDONA, R
GAILLARD, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) : 6347 - 6354
[8] OXIDATION OF PHENOLS WITH MOLECULAR-OXYGEN CATALYZED BY [N,N'-BIS(2'-PYRIDINECARBOXAMIDO)-1,2-BENZENE]COBALT(II),CHELATE
GANESHPURE, PA
SUDALAI, A
SATISH, S
[J]. TETRAHEDRON LETTERS, 1989, 30 (43) : 5929 - 5932
[9] POLYMERIZATION BY OXIDATIVE COUPLING
HAY, AS
BLANCHARD, HS
ENDRES, GF
EUSTANCE, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (23) : 6335 - 6336
[10] HYDROGEN-PEROXIDE OXIDATION CATALYZED BY HETEROPOLY ACIDS COMBINED WITH CETYLPYRIDINIUM CHLORIDE - EPOXIDATION OF OLEFINS AND ALLYLIC ALCOHOLS, KETONIZATION OF ALCOHOLS AND DIOLS, AND OXIDATIVE CLEAVAGE OF 1,2-DIOLS AND OLEFINS
ISHII, Y
YAMAWAKI, K
URA, T
YAMADA, H
YOSHIDA, T
OGAWA, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) : 3587 - 3593

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