STRUCTURE OF DI-MU-CYANATO-BIS[CYANATO(N,N-DIETHYLETHYLENEDIAMINE)COPPER(II)], [CU(NCO)2(DIETEN)]2

被引：23

作者：

ZUKERMANSCHPECTOR, J ^{[1
]}

CASTELLANO, EE ^{[1
]}

DESIMONE, CA ^{[1
]}

OLIVA, G ^{[1
]}

MAURO, AE ^{[1
]}

机构：

[1] UNIV NACL ESTADUAL SAO PAULO,INST QUIM ARARAQUARA,BR-14800 ARARAQUARA,SP,BRAZIL

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190011416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Cu2(NCO)4(C6N2H16)2], M(r) = 527.56, monoclinic, P2(1)/c, a = 11.586 (2), b = 7.279 (1), c = 13.742 (2) angstrom, beta = 96.02 (2)degrees, V = 1152.5 (6) angstrom 3, Z = 2, D(x) = 1.520 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 18.87 cm-1, F(000) = 548, T = 296 K, R = 0.033 for 1393 observed reflections. The compound is in a dimeric form. Each metal atom is coordinated to five N atoms: two from one diEten group [Cu-N = 2.102 (3), 1.974 (3) angstrom], one from a terminal cyanate group [Cu-N = 1.938 (4) angstrom] and two belonging to bridging cyanate groups [Cu-N = 2.017 (3), 2.450 (4) angstrom], giving rise to a distorted, elongated square-pyramidal configuration. The Cu...Cu distance is 3.236 (1) angstrom. Dimers are linked through H bonds involving the O of the bridging cyanate and the NH2 end of diEten [N(4)...O(1)(- x, - 1 - y, 1 - z) = 2.943 (5) angstrom, N(4)-H(4)...O(1) = 165.2 (2)-degrees].

引用

页码：957 / 959

页数：3

共 17 条

[1] STRUCTURE AND MAGNETIC-PROPERTIES OF NOVEL 1,1-AZIDO-BRIDGED AND 1,1-CYANATO-BRIDGED BINUCLEAR COPPER(II) COMPLEXES [J].

BOILLOT, ML ;

KAHN, O ;

OCONNOR, CJ ;

GOUTERON, J ;

JEANNIN, S ;

JEANNIN, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (03) :178-180

[2]

BURMEISTER JL, 1969, INORG CHIM ACTA, V3, P479

[3] SYNTHESIS AND SOLID-STATE STRUCTURAL CHARACTERIZATION OF DI-MU-AZIDO-BIS[(AZIDO(NORMAL,NORMAL-DIETHYLETHYLENEDIAMINE))COPPER(II)] [J].

CASAGRANDE, OL ;

KLEIN, SI ;

MAURO, AE ;

TOMITA, K .

TRANSITION METAL CHEMISTRY, 1989, 14 (01) :45-47

[4] MAGNETIC EXCHANGE INTERACTIONS IN SOME NOVEL MU-AZIDO-BRIDGED COPPER(II) DIMERS - CRYSTAL-STRUCTURES OF [L2CU2(MU-N3)(N3)2](CLO4).H2O, LCU(N3)2, [L2CU2(MU-N3)2(CLO4)2], AND L'CU(N3)2 (L = N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE AND L' = 1,4,7-TRIAZACYCLONONANE) [J].

CHAUDHURI, P ;

ODER, K ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J .

INORGANIC CHEMISTRY, 1986, 25 (16) :2818-2824

[5] STRUCTURE OF MONOAQUABIS(ISOCYANATO)(2,2'-6',2''-TERPYRIDYL)NICKEL(II) [J].

CORTES, R ;

ARRIORTUA, MI ;

ROJO, T ;

MESA, JL ;

SOLANS, X ;

BELTRAN, D .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :986-990

[6] RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS [J].

CROMER, DT ;

LIBERMAN, D .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) :1891-&

[7] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].

CROMER, DT ;

MANN, JB .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&

[8]

JOHNSON CK, 1965, ORNL3794 REP

[9] CRYSTAL-STRUCTURE OF BIS(ISOCYANATO)(2,2'-6',2''-TERPYRIDYL)COBALT(II) - STEREOCHEMISTRY OF [M(TRIDENTATE LIGAND)(UNIDENTATE LIGAND)2] COMPLEXES [J].

KEPERT, DL ;

KUCHARSKI, ES ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (10) :1932-1938

[10]

MAURO AE, 1990, UNPUB POLYHEDRON

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